J. de Groot, T. Mueller, R. A. Rosenberg, D. J. Keavney, Z. Islam, J. -W. Kim, M. Angst
We present the refinement of the crystal structure of charge-ordered LuFe2O4, based on single-crystal x-ray diffraction data. The arrangement of the different Fe-valence states, determined with bond-valence-sum analysis, corresponds to a stacking of charged Fe bilayers, in contrast to the polar bilayers previously suggested. This arrangement is supported by an analysis of x-ray magnetic circular dichroism spectra, which also evidences a strong charge-spin coupling. The non-polar bilayers are inconsistent with charge order based ferroelectricity.
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http://arxiv.org/abs/1112.0978
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