1208.2652 (Katrin Sedlmeier et al.)

Absence of charge order in the dimerized κ-phase BEDT-TTF salts    [PDF]

Katrin Sedlmeier, Sebastian Elsasser, Rebecca Beyer, Dan Wu, Tomislav Ivek, Silvia Tomic, John A. Schlueter, Martin Dressel

Utilizing infrared vibrational spectroscopy we have investigated dimerized two-dimensional organic salts in order to search for possible charge redistribution that might cause electronic dipoles and ferroelectricity: the quantum spin liquid \kappa-(BEDT-TTF)2Cu2(CN)3, the antiferromagnetic Mott insulator \kappa-(BEDT-TTF)2$Cu[N(CN)2]Cl, and the superconductor \kappa-(BEDT-TTF)2$Cu[N(CN)2]Br. None of them exhibit any indication of charge disproportionation upon cooling down to low temperatures. No modification in the charge distribution is observed around T = 6 K where a low-temperature anomaly has been reported for the spin-liquid \kappa-(BEDT-TTF)2$Cu2(CN)3. In this compound the in-plane optical response and vibrational coupling are rather anisotropic, indicating that the tilt of the BEDT-TTF molecules in c-direction and their coupling to the anion layers has to be considered in the explanation of the electromagnetic properties.

View original: http://arxiv.org/abs/1208.2652