1011.3314 (Zhe Wang et al.)

Orbital fluctuations and orbital order below the Jahn-Teller transition
in Sr3Cr2O8    [PDF]

Zhe Wang, M. Schmidt, A. Günther, S. Schaile, N. Pascher, F. Mayr, Y. Goncharov, D. L. Quintero-Castro, A. T. M. N. Islam, B. Lake, H. -A. Krug von Nidda, A. Loidl, J. Deisenhofer

We report on the magnetic and phononic excitation spectrum of Sr3Cr2O8 determined by THz and infrared (IR) spectroscopy, and electron spin resonance (ESR) measurements across the Jahn-Teller transition, which is detected by specific-heat measurements to occur at T_{JT} = 285 K. We identify the singlet-triplet excitations in the dimerized ground state and estimate the exchange couplings in the system. Moreover, ESR absorptions were observed up to T* = 120 K with a linewidth proportional to exp{-Delta/k_{B}T} and Delta/k_{B} = 388 K indicating a phonon-mediated spin relaxation via the excited orbital state of the Cr $e$ doublet in the orbitally ordered state. In contrast to the expected drastic change of the IR active phonons upon entering the low-symmetry Jahn-Teller distorted phase below T_{JT}, we find an extended regime T*View original: http://arxiv.org/abs/1011.3314